Reaction Kinetics of Tert-Butanol Esterification
نویسندگان
چکیده
In this study, the kinetics for reaction of tert-butanol esterification with acetic acid in presence Dowex 50Wx8 catalyst was investigated. The kinetic experiments were conducted 1000 milliliter vessel at temperatures ranged from 50 - 80 oC, loading 25-50 g/L, and molar ratios to 1/3 – 3/1. rate found increase increasing temperature loading. It also conversion increases as ratio alcohol Non-ideality liquid phase taken into account by using activities instead fractions. activity coefficients calculated according group contribution UNIFAC method. results show that activation energy be 1.09 kJ/mol.
منابع مشابه
Study of reaction parameters and kinetics of esterification of lauric acid with butanol by immobilized Candida antarctica lipase.
Esterification of lauric acid with n-butanol, catalyzed by immobilized Candida antarctica lipase (CAL) in aqueous-organic biphasic solvent system was studied. Effects of various reaction parameters on esterification were investigated, such as type and amount of solvent, amount of buffer, pH, temperature, speed of agitation, amount of enzyme, butanol and lauric acid. The most suitable reaction c...
متن کاملKinetics and thermodynamics of the esterification reaction according to the Langmuir-Hinshelwood mechanism
In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...
متن کاملKinetics and thermodynamics of the esterification reaction according to the Langmuir-Hinshelwood mechanism
In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...
متن کاملEsterification Reaction Kinetics Using Ion Exchange Resin Catalyst by Pseudo-Homogenous and Eley-Ridel Models
This work deals with kinetics and chemical equilibrium studies of esterification reaction of ethanol with acetic acid. The esterification reaction was catalyzed by an acidic ion exchange resin (Amberlyst-15) using a batch stirred tank reactor. The pseudo-homogenous and Eley-Rideal models were successfully fitted with experimental data. At first, Eley-Rideal model was examined for heterogeneous...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Ma?allat? al-handasat?
سال: 2023
ISSN: ['1726-4073', '2520-3339']
DOI: https://doi.org/10.31026/j.eng.2014.12.05